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主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
含磷回收物对甲烷/煤尘复合爆炸火焰传播的抑制效果及机理研究
  • Title

    Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion

  • 作者

    刘丽孟祥豹陈记合张延松王桐石磊吴阳吴琦岩

  • Author

    LIU Li;MENG Xiangbao;CHEN Jihe;ZHANG Yansong;WANG Tong;SHI Lei;WU Yang;WU Qiyan

  • 单位

    山东科技大学 安全与环境工程学院青岛市生产安全火灾重大事故智能控制工程研究中心山东科技大学 公共安全研究院中国安全生产科学研究院

  • Organization
    College of Safety and Environmental Engineering, Shandong University of Science and Technology
    Qingdao Intelligent Control Engineering Center for Production Safety Fire Accident
    Institute of Public Safety, Shandong University of Science and Technology
    China Academy of Safety Science and Technology
  • 摘要

    磷酸铵镁(MgNH4PO4·6H2O)是污水处理管道中易生成的一种含磷管道堵塞物,为研究其对甲烷/煤尘复合爆炸的抑制效果,对磷酸铵镁晶体颗粒进行机械化学改性,制备了分散性良好的磷酸铵镁粉体(S-MAP),并用改进的哈特曼火焰传播实验系统研究了不同质量分数(20%、40%、60%、80%)的S-MAP对甲烷/煤尘复合爆炸火焰传播的抑制效果。实验结果表明:S-MAP的加入可以显著降低火焰传播速度、高度和亮度;随着S-MAP质量分数的提高,火焰传播高度由高于900 mm降低至134 mm,火焰传播平均速度由8.76 mm/ms降低至0.51 mm/ms;当S-MAP质量分数达到80%时,整个火焰传播过程只呈现微小火焰,可抑制住火焰的传播;抑爆机理方面,S-MAP分解能够吸收大量的热量起冷却作用,热分解产生的中间体能够吸附爆炸自由基以阻断爆炸链反应起吸附爆炸自由基作用,热分解产物能够稀释爆炸空间内氧气和可燃气体的浓度,同时热分解产物能够吸附在煤尘表面而隔绝氧气和热量的传递起窒息作用,三者的耦合效应抑制了甲烷/煤尘爆炸火焰的传播过程。

  • Abstract

    Magnesium ammonium phosphate (MgNH4PO4·6H2O) is a phosphorus-containing blockage commonly found in sewage treatment pipelines. In order to study its suppression effect on the methane/coal dust composite explosion, magnesium ammonium phosphate was subjected to mechanized chemical modification to prepare well-dispersed magnesium ammonium phosphate powder (S-MAP). The improved Hartmann flame propagation system was used to investigate the suppression effect of different mass fractions of S-MAP(20%, 40%, 60%, 80%)on the flame propagation of the methane/coal dust composite explosion. The experimental results indicate that the addition of S-MAP can significantly reduce flame propagation speed, height, and brightness. With the increase of S-MAP addition ratio, the flame propagation height decreased from over 900 mm to 134 mm, and the average flame propagation speed decreased from 8.76 mm/ms to 0.51 mm/s. When the S-MAP addition ratio reached 80%, the entire flame propagation process only presented small flames, which could suppress the propagation of flames; in terms of explosion suppression mechanism, S-MAP decomposition can absorb a large amount of heat, thereby exerting a cooling effect. The intermediate produced by thermal decomposition of S-MAP can adsorb explosion free radicals to block the explosion chain reaction, thereby exerting the effect of adsorbing explosive free radicals. The thermal decomposition products of S-MAP can dilute the concentration of oxygen and combustible gases in the explosion space, and at the same time, the thermal decomposition products can adsorb on the surface of coal dust to isolate the transfer of oxygen and heat, thereby exerting a suffocating effect. The coupling effect of the three suppresses the propagation process of methane/coal dust explosion flames.

  • 关键词

    磷酸铵镁二氧化硅甲烷/煤尘复合爆炸火焰传播抑制机理

  • KeyWords

    magnesium ammonium phosphate;silica;methane/coal dust composite explosion;flame propagation;suppression mechanism

  • 基金项目(Foundation)
    国家自然科学基金资助项目(52074174);中国安全科学技术研究院基础科研业务费专项基金资助项目(2023JBKY01)
  • DOI
  • 引用格式
    刘丽,孟祥豹,陈记合,等. 含磷回收物对甲烷/煤尘复合爆炸火焰传播的抑制效果及机理研究[J]. 煤矿安全,2025,56(3):75−83.
  • Citation
    LIU Li, MENG Xiangbao, CHEN Jihe, et al. Study on suppression effect and mechanisms of phosphorus-containing recycling substance on flame propagation of methane/coal dust composite explosion[J]. Safety in Coal Mines, 2025, 56(3): 75−83.
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