• 论文
主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
纳米多级孔SAPO-11分子筛制备及其催化2-甲基萘烷基化反应
  • Title

    Preparation of hierarchical nano-SAPO-11 zeolites as catalystsfor the synthesis of 2,6-dimethylnaphthalene

  • 作者

    张晓华张璞纪琳江乐杰宋艳萍魏海国曾庆峰叶闰平冯刚

  • Author

    ZHANG Xiaohua;ZHANG Pu;JI Lin;JIANG Lejie;SONG Yanping;WEI Haiguo;ZENG Qingfeng;YE Runping;FENG Gang

  • 单位

    中国石油天然气股份有限公司规划总院中国石油炼油化工和新材料分公司辽河油田油气集输公司南昌大学

  • Organization
    PetroChina Refining,Chemicals & New MaterialsCompany
    Liaohe Oilfield Oil and Gas Gathering and Transportation Company
    School of Chemistry and Chemical Engineering,Nanchang University
  • 摘要

    SAPO-11分子筛作为微孔沸石,通常粒径大,如何在水热法基础上进一步合成纳米多级孔SAPO-11分子筛极具挑战。在水热合成SAPO-11分子筛基础上,通过对前驱体凝胶进行老化处理制备纳米多级孔SAPO-11分子筛。其中,在80℃用搅拌老化制备的SAPO-11分子筛有最小晶体尺寸,通过SEM可知通过搅拌老化制备的S11-80℃-stirring分子筛呈现一种均匀纳米棒状结构,这些纳米棒的直径约500~700nm,长度约2~4μm。2-甲基萘(2-MN)主要来源于煤焦油,可用于制备2,6-二甲基萘(2,6-DMN),用于合成高端聚酯,为此将上述纳米多级孔SAPO-11分子筛用于催化2-甲基萘烷基化反应,结果表明使用老化处理制备的纳米多级孔SAPO-11分子筛有77.8%的2-MN初始转化率,20.4%的初始选择性,2,6-DMN、2,7-DMN的什么比为1.13,反应第4小时2,6-DMN选择性最高,为39.9%,通过系列表征揭示了纳米多级孔SAPO-11分子筛择形催化催化机理。

  • Abstract

    As a microporous zeolite, SAPO - 11 zeolites usually have a large particle size, but how to further synthesize hierarchicalnano-SAPO-11 zeolites on the basis of hydrothermal method is a great challenge. Based on the hydrothermal method,SAPO-11 zeoliteswere prepared by aging treatment with the precursor gel. Among them,the SAPO-11 zeolites prepared by stirring aging treatment at 80 ℃has the smallest crystal size. It can be seen by SEM that the S11-80 ℃ -stirring zeolite show a uniform nanorod-like structure,these nanorods have a diameter of about 500-700 nm and a length of about 2-4 μm. 2-Methylnaphthalene (2-MN),which is mainly derivedfrom coal tar,can be used to prepare 2,6-dimethylnaphthalene (2,6-DMN),and then be used to synthesize high-end polyester. Therefore,the above-mentioned hierarchical nano-SAPO-11 zeolites were applied to catalyze the alkylation reaction of 2-methylnaphthalene.The results show that the SAPO-11 zeolites prepared by aging treatment have 77.8% initial conversion of 2-MN,20.4% initial selectivity,1.13 ratio of 2,6- DMN / 2,7-DMN,and the highest selectivity of 2,6-DMN of 39.9% at the 4th hour of reaction. The shape selection catalytic mechanism of SAPO-11 molecular sieve was revealed by series characterization.

  • 关键词

    多级孔SAPO-11老化处理烷基化26-二甲基萘

  • KeyWords

    hierarchical pore;SAPO-11;aging treatment;alkylation;2,6-dimethylnaphthalene

  • 基金项目(Foundation)
    国家自然科学基金资助项目(22362022;21875096),江西省双高项目。
  • DOI
  • 引用格式
    张晓华,张璞,纪琳,等.纳米多级孔SAPO-11分子筛制备及其催化2-甲基萘烷基化反应[J].洁净煤技术,2024,30(8):162-169.
  • Citation
    ZHANG Xiaohua,ZHANG Pu, JI Lin, et al. Preparation of hierarchical nano - SAPO - 11 zeolites as catalysts for thesynthesis of 2,6-dimethylnaphthalene[J].Clean Coal Technology,2024,30(8):162-169.
  • 相关专题
  • 图表
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    • 老化处理制备的SAPO-11分子筛XRD图

    图(6) / 表(0)

相关问题

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