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热解褐煤的渗透性与微细观结构
  • Title

    Permeability and microstructure of pyrolysis lignite

  • 作者

    李亚军孟巧荣陈涛林峰

  • Author

    LI Yajun;MENG Qiaorong;CHEN Tao;LIN Feng

  • 单位

    太原理工大学矿业工程学院

  • Organization
    College of Mining Engineering, Taiyuan University of Technology
  • 摘要

    为了研究褐煤热解过程中,热流固耦合作用下的微细观孔裂隙结构对渗透性的影响,利用太原理工大学μCT225kVFCB 型高精度显微CT 试验系统和自主研制的高温加热气氛炉,对低温热解褐煤进行实时CT 扫描,结合三维可视化重构软件AVIZO 对褐煤的微细观结构进行研究分析。通过对褐煤的有效孔裂隙的提取分析,从Kozeny-Carman 渗透率估算方程与达西定律2 种角度研究了无应力状态下的褐煤的渗透性和孔裂隙结构随温度的演化过程,结果表明:① 从室温~600 ℃,演化过程可以分为3 个阶段:第1 阶段,常温~300 ℃,煤体热破裂,导致大量孔裂隙产生,渗透率快速增加,发生量级变化;第2 阶段为300~500 ℃,煤基质热解,新的热解产物改变了流体通道,使渗透率缓慢下降;第3 阶段为500~600 ℃,渗透率又开始增加,渗透率进入下一个快速增加阶段;② 300 ℃ 时,褐煤的渗透率达到了15.5×10−12 m2,煤体基本完全渗透;③ 热流固耦合作用下,褐煤热解渗透率不仅取决于孔裂隙微细观结构,而且与流体在煤基质中的流动特性有关,随温度的增加,流体的传热传质特性对渗透率的影响越来越明显;④ 基于孔裂隙结构参数的Kozeny-Carman方程估算的渗透率和绝对渗透率相差不大,基本可以反应渗透率随温度的变化关系。基于真实孔裂隙结构上的渗透率估算可以大大减少高温高压渗流实验强度,为简化和验证岩体渗透试验提供一种方法。

  • Abstract
    In order to study the influence of micro pore fissure structure on permeability under the thermal-fluid-solidcoupling during lignite pyrolysis, real-time CT scanning of lignite during low-temperature pyrolysis was carried out by usingthe μCT225kVFCB high-precision micro-CT test system of Taiyuan University of Technology, combined with the selfdevelopedhigh-temperature atmosphere furnace. The micro-structure of lignite was studied and analyzed with AVIZOsoftware. Through the extraction and analysis of the effective pore and fissure of lignite, the evolution process of the permeabilityof lignite under non-stress condition with temperature was studied from the perspectives of Kozeny-Carman permeabilityestimation equation and Darcy’s law. The results show that: ① From room temperature to 600 ℃, the evolutionprocess can be divided into three stages: the first stage, at room temperature to 300 ℃, thermal cracking occurs in the coalbody, resulting in the generation of a large number of pores and fissures, and the permeability increases by orders of magnitude.The second stage is at 300 to 500 ℃, the coal matrix is pyrolysed and the new pyrolysis products change the fluid channels, causing a slow decrease in permeability. The third stage is at 500 to 600 ℃, permeability begins to increaseagain, permeability enters the next rapid increase stage. ② At 300 ℃, the permeability of lignite reaches 15.5×10−12 m2,and the coal body is basically completely penetrated. ③ Under the thermal-fluid-solid coupling, the pyrolysis permeabilityof lignite depends not only on the micro-structure of pores and fissures, but also on the flow characteristics of fluid inthe coal matrix. With the increase of temperature, the influence of heat and mass transfer characteristics of fluid on the permeabilitybecomes more and more obvious. ④ The permeability estimated by Kozeny-Carman equation based on pore fissurestructure parameters is similar to the absolute permeability, which can basically reflect the relationship between permeabilityand temperature. The permeability estimation based on the real pore fissure structure can greatly reduce the difficultyof seepage experiment at high temperature and pressure, and provide a method for simplifying and verifying theseepage experiment of rock mass.
  • 关键词

    热解褐煤渗透率CT三维裂隙网络

  • KeyWords

    pyrolysis lignite;permeability;CT;three-dimensional fissure network

  • 基金项目(Foundation)
    国家自然科学基金面上资助项目(51974191);山西省省筹资助回国留学人员资助项目(2021-059)
  • DOI
  • 引用格式
    李亚军,孟巧荣,陈涛,等. 热解褐煤的渗透性与微细观结构[J]. 煤炭学报,2023,48(4):1707−1714
  • Citation
    LI Yajun,MENG Qiaorong,CHEN Tao,et al. Permeability and microstructure of pyrolysis lignite[J]. Journal of China Coal Society,2023,48(4):1707−1714
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