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主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
国外某铁矿氢基矿相转化—弱磁选—反浮选实验研究
  • Title

    Hydrogen−based Mineral Phase Transformation−low Intensity Magnetic Separation−reverse Flotation of an Iron Ore Abroad

  • 作者

    宁国栋刘鸿刘应志李文明

  • Author

    NING Guodong;LIU Hong;LIU Yingzhi;LI Wenming

  • 单位

    上海逢石科技有限公司

  • Organization
    Shanghai Milestone Technology Co., LTD
  • 摘要

    某铁矿铁品位为52.11%,铁主要以赤/褐铁矿的形式存在,占全铁的85.54%,主要脉石矿物为石英,含量为20.87%。为确定该矿石的合理利用工艺,进行了氢基矿相转化—弱磁选—反浮选实验研究。结果表明,在还原温度为540 ℃、还原时间为20 min、还原气体体积浓度为25%,还原气氛V(CO)∶V(H2)=1∶3,磨矿细度−0.074 mm含量占72%、磁场强度为1600 Gs的条件下,可以得到磁选精矿铁品位65.55%、铁回收率98.14%的指标;磁选精矿中铁主要存在于磁性铁中,赤/褐铁矿的含量降为0.20%,说明原矿经氢基矿相转化后,弱磁性的赤/褐铁矿物被还原为强磁性的磁铁矿,在弱磁选过程中铁矿物得到有效回收。将磁选精矿磨细至−0.074 mm含量为88%,经一次粗选一次精选一次扫选反浮选实验可以获得铁品位68.47%、回收率97.48%(对原矿95.61%)的最终精矿,SiO2含量为3.06%,比原矿降低约18百分点。“氢基矿相转化—弱磁选—反浮选”工艺是处理该矿石的适宜工艺,具有巨大的经济、社会和环境效益,提升了矿产资源高质量利用能力、资源持续保障能力和市场风险防范能力。

  • Abstract

    China's iron ore is heavily dependent on imports. In order to solve the problem of import dependence, enterprises are actively searching for available iron ore resources and developing independent innovation technologies. The hydrogen−based mineral phase conversion technology uses hydrogen or hydrogen−rich gas as a reducing agent to chemically react the ore in a suspended state and at a certain temperature, so that the weakly magnetic iron minerals in the ore are converted into strong magnetic magnetite or maghemite, and then magnetic separation is performed using magnetic differences between minerals. The iron grade of an iron ore is 52. 11%. Iron mainly exists in the form of hematite/limonite, accounting for 85. 54% of total iron. The main gangue mineral is quartz, with a content of 20. 87%. In order to determine the reasonable utilization process of the ore, the experimental study of hydrogen−based mineral phase transformation−low intensity magnetic separation−reverse flotation was carried out. The results show that when the reduction temperature is 540 ℃, the reduction time is 20 min, the reduction gas volume concentration is 25%, the reduction atmosphere V(CO)∶V(H2)=1∶3, the grinding fineness −0. 074 mm content accounts for 72%, and the magnetic field strength is1600 Gs, the magnetic concentrate iron grade is 65. 55%, and the iron recovery rate is 98. 14%. The iron in the magnetic separation concentrate mainly exists in the magnetic iron. Compared with the iron content in the magnetic iron of the raw ore, the iron content in the magnetic iron increases by about 58%, and the content of hematite/limonite decreases to 0. 20%, indicating that the weak magnetic hematite/limonite minerals are reduced to strong magnetic magnetite after the conversion of the raw ore by the hydrogen−based mineral phase, and the iron minerals are effectively recovered during the weak magnetic separation process. The magnetic separation concentrate was ground to −0. 074 mm content of 88%. After one roughing, one cleaning and one scavenging reverse flotation test, the final concentrate with iron grade of 68. 47% and recovery rate of 97. 48% was obtained. The SiO2 content was 3. 06%, which was about 18 percentage points lower than that of the raw ore. In this paper, through the process of ' hydrogen−based mineral phase transformation−low intensity magnetic separation−reverse flotation ', the experimental research on iron extraction and impurity reduction is completed. It is a suitable process for treating the ore. The process has great economic, social and environmental benefits, and improves the high−quality utilization of mineral resources. Ability, resource sustainability and market risk prevention capabilities.

  • 关键词

    赤/褐铁矿氢基矿相转化反浮选提铁降杂

  • KeyWords

    hematite/limonite;hydrogen−based mineral phase transformation;reverse flotation;raise iron and reduce impurities

  • DOI
  • 引用格式
    宁国栋,刘鸿,刘应志,李文明. 国外某铁矿氢基矿相转化—弱磁选—反浮选实验研究[J]. 矿产保护与利用,2025,45(1):53−59.
  • Citation
    NING Guodong,LIU Hong,LIU Yingzhi,LI Wenming.Hydrogen−based mineral phase transformation−low intensity magnetic separation−reverse flotation of an iron ore abroad[J]. Conservation and Utilization of Mineral Resources,2025,45(1):53−59.
  • 图表
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    • 原矿XRD图谱

    图(8) / 表(8)

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