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主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
黔北地区页岩孔隙结构特征及水渗流演化规律研究
  • Title

    Study on characteristics of shale pore structure and water seepage evolution laws in northern Guizhou

  • 作者

    李波波陈帅杨康李建华任崇鸿

  • Author

    LI Bobo,CHEN Shuai,YANG Kang,LI Jianhua,REN Chonghong

  • 单位

    贵州大学 矿业学院贵州大学 喀斯特山区优势矿产资源高效利用国家地方联合工程实验室贵州省非金属矿产资源综合利用重点实验室

  • Organization
    1.College of Mining, Guizhou University, Guiyang ,China;2.The National Joint Engineering Laboratory for the Utilization of Dominant Mineral Resources in Karst Mountain Area, Guizhou University, Guiyang ,China;3.Guizhou Provincial Key Laboratory of Comprehensive Utilization of Non-metallic Mineral Resources, Guiyang ,China
  • 摘要

    为探究页岩孔隙结构特征以及水渗流演化规律, 以黔北地区牛蹄塘组页岩为研究对象,首先采用低温液氮吸附试验以及高压压汞试验分析页岩内部微观孔隙结构特征,然后在恒定围压、轴压条件下利用三轴渗流装置进行了不同有效应力条件下的三轴渗流试验,探讨页岩有效应力与渗透率之间的关系,建立了考虑孔隙结构和压缩特性联动影响的页岩渗透率模型,并通过与初始渗透率受应力状态下的页岩渗透率模型对比分析验证其合理性。结果表明:黔北地区牛蹄塘组页岩是一个从微孔到大孔的连续分布体系,5种页岩的吸附-脱附等温曲线其类型与IUPAC分类中的Ⅳ型最为接近而且进汞-退汞曲线形态近似,大孔的类型以一端封闭的不透气孔为主,中孔则以两端开放的毛细孔等开放型孔为主,微孔主要以细颈广体孔和墨水瓶孔为主;页岩孔径分布复杂,含有大量的微孔和中孔,其中微孔和中孔提供了大部分孔比表面积,而大孔则是孔体积的主要贡献者;在相同围压、轴压条件下,页岩渗透率随着有效应力的增大呈逐渐减小的趋势,且渗透率和有效应力呈指数函数关系;考虑孔隙结构和压缩特性联动影响的页岩渗透率模型计算曲线与渗透率试验所测的数据基本吻合,且能很好反映恒定围压、轴压条件下有效应力与渗透率之间的变化关系。

  • Abstract
    In order to reveal the characteristic pore structure of shale and the evolution rules of water seepage, studies were carried out for the Niutitang Formation shale in northern Guizhou .First, low temperature liquid nitrogen adsorption test and high pressure mercury injection test were employed to analyze the internal micro-pore structure of the shale.Then, under the condition of constant confining pressure and axial pressure, the triaxial seepage tests were carried out using triaxial seepage device under different effective stresses, and the relationship between effective stress and permeability of shale is discussed.A shale permeability model was constructed by considering the linkage effect of pore structure and compression characteristics, and the study results were verified by comparative analysis with the shale permeability model under the stress state of initial permeability.Study results show that the Niutitang Formation shale has a continuous distribution system with the range from micro pore to macro pore, the adsorption-desorption isothermal adsorption curves of the five types of shale have closest similarity with the Type Ⅳfrom the IUPAC Classification and there is consistency between the mercury forming-mercury withdrawing curves; The dominating type of macro-pore is the one of air-tightening with one end closed, most of the meso-pore are open pores such as capillary with both ends open, the main micro-porous main are those of thin neck wide bore body and the ink bottle;The pore size distribution of shale is rather complex, containing a large number of micro-pores and meso-pores, both of which contribute the most of the pore specific surface area, while the macro pore are the main contributor for pore volume; Under the same confining pressure and axial pressure, shale permeability decreases gradually with the increase of effective stress following a exponential relationship;After taking into account of the linkage effect of pore structure and compression characteristics,the calculated curve from shale permeability model is generally consistent with the experimental data from permeability test, and can well reflect the relationship between effective stress and permeability under constant confining pressure and axial pressure.
  • 关键词

    页岩气孔隙结构孔径比表面积渗透率

  • KeyWords

    shale gas; pore structure; aperture; specific surface area; permeability

  • 基金项目(Foundation)
    国家自然科学基金资助项目(51804085,51911530203);贵州省科技计划资助项目(黔科合平台人才[2018]5781号)
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