Weakening and fracturing mechanism of mechanical properties of coal and rock caused by supercritical CO2
LIANG Weiguo,HE Wei,YAN Jiwei
含煤地层中含有大量的煤系气资源,高效开采煤系气资源对非常规油气资源开发利用与能 源革命具有重要意义与价值。 含煤地层中煤层与其他岩层叠置发育,增加了煤系气开采的难度。 在实验室进行了超临界 CO2(ScCO2)对含煤地层中的砂岩、煤样长时浸泡作用实验及其力学变化 特征的研究,并结合显微 CT 扫描,研究了水力压裂、液态 CO2 压裂和 ScCO2 压裂煤体后的裂缝分布 特征,揭示了煤样、砂岩在液态CO2与ScCO2压裂时的破裂特征及裂纹扩展控制机理。 研究结果表 明:1 ScCO2 浸泡对煤体力学特性弱化作用强于其对顶板砂岩力学特性的弱化。 ScCO2 浸泡 15,30 到 60 d 后,砂岩单轴抗压强度分别降低了 9.10%,21.97%和 48.93%,砂岩的弹性模量分别减小了12.70%,18.82%和 27.19%。 ScCO2 浸泡作用 20 d 后,弱黏煤、1 / 3 焦煤、贫瘦煤和无烟煤的单轴抗 压强度分别降低 65.25%,45.24%,56.02%和 67.94%,弹性模量分别降低 65.87%,52.50%,57.14% 和 65.91%。 2 煤体吸附 CO2 后膨胀变形导致其表面能减小,ScCO2 对煤中有机物的萃取及其进入 煤体微小孔裂隙内部导致煤体的孔隙压力增大,CO2 与水结合形成碳酸对煤中矿物的溶解是导致 煤体力学强度降低的主要因素。 3 含煤地层中 ScCO2 压裂优于水力压裂。 ScCO2 能够大幅降低煤 体、岩体的力学强度,减小煤体、岩体的破裂压力;CO2 分子能够进入到煤体、岩体的裂隙尖端,加速 煤岩体的损伤破坏,并形成多分叉、高曲折度、扩展距离远的复杂裂缝网络结构。
Coal bearing strata contain a large amount of gasbearing coal resources,and efficient exploitation of gasbearing coal resources is of great significance to the development and utilization of unconventional gas resources and energy revolution. The development of coal seams superimposed on other rock layers in coal bearing strata increases the difficulty of extracting gasbearing coal. In this paper,the longterm saturation effect of supercritical CO 2(ScCO 2) on sandstone and coal samples in coal bearing strata and their mechanical variation characteristics was carried out in the laboratory,and the distribution characteristics of cracks after hydraulic fracturing,liquid CO 2 fracturing and ScCO 2 fracturing in coal with CT scanning are studied. The fracturing characteristics and crack propagation mechanism of coal samples and sandstone during liquid CO 2 and ScCO 2 fracturing are revealed. The results show that:① The weakening of mechanical properties of coal by ScCO2 is stronger than that of roof sandstone. The uniaxial compressive strength of sandstone is decreased by 9.10%,21.97% and 48.93% on average with the ScCO 2 saturation time increase from 15,30 to 60 days,and the elastic modulus is also decreased by 12.70%,18.82% and 27.19% on average accordingly. After saturation in ScCO 2 for 20 days,the uniaxial compressive strength of weakly caking coal,1/3 coking coal,lean coal and anthracite is decreased by 65.25%,45.24%,56.02% and 67.94%,and the elastic modulus is also decreased by 65.87%,52.50%,57.14% and 65.91%,respectively.② The main factors leading to the reduction of mechanical strength of coal are the surface energy of coal decreases due to the expansion and deformation of coal after CO 2 adsorption,the extraction of organic matter by ScCO 2 and the ScCO 2 enters into the tiny pores and fissures of coal that increases the pore pressure of coal,and the dissolution of coal minerals by carbonic acid formed by CO2 combined with water.③ ScCO2 fracturing is better than hydraulic fracturing in coal bearing strata. ScCO2 can greatly reduce the mechanical strength of coal and rock mass,thus reducing the fracture pressure. CO 2 molecules can enter the fracture tips of coal and rock mass,accelerating their damage and destruction and forming complex fracture network structures with multiple bifurcations,high tortuosity and long extension distances.
coal bearing strata,mechanical properties,carbon dioxide fracturing,crack propagation,supercritical CO2
主办单位:煤炭科学研究总院有限公司 中国煤炭学会学术期刊工作委员会