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Title
Application research status and development trend of coal⁃based activatedcarbon in China
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作者
陈文凯胡子晗白效言熊银伍李小亮郭昊乾
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Author
CHEN Wenkai;HU Zihan;BAI Xiaoyan;XIONG Yinwu;LI Xiaoliang;GUO Haoqian
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单位
煤炭科学技术研究院有限公司国家能源煤炭高效利用与节能减排技术装备重点实验室煤基节能环保炭材料北京市重点实验室
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Organization
China Coal Research Institute Corporation Ltd.
National Energy Technology &Equipment Laboratory of Coal Utilization and Emission Control
Beijing Key Laboratory of Coal⁃based Carbon Materials
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摘要
煤基活性炭应用是煤炭清洁高效利用的重要组成部分,基于煤基活性炭具有孔隙结构发达、物理化学性质稳定、吸附性能优良、催化性能佳、易再生等特点而被广泛应用于众多领域,因此研究和归纳我国煤基活性炭的应用研究现状与发展趋势具有重要意义。对近年我国煤基活性炭的应用研究进行归纳分析,阐述煤基活性炭在我国主要应用领域的研究特点,具体探讨其在液相吸附(如水处理、食品加工、贵金属回收、医药领域等)、气相吸附(如烟气净化、挥发性有机物处理等)、催化领域(如催化剂、催化剂载体等)以及超级电容器、电极材料、土壤改良、气体分离、香烟滤器等其他方面的应用研究现状,并展望我国煤基活性炭的研究发展趋势。煤基活性炭可广泛用于市政自来水净化、生活污水与工业污水处理、医药废水处理等水处理领域,同时广泛应用于食品的脱色、除味、纯化等食品加工领域,也已将其大量应用于使用活性炭提取黄金等贵金属及与药物合成中间产物提纯和脱色精制等领域。煤基活性炭在气相吸附领域应用主要体现在烟气净化、挥发性有机物处理等,其技术应用具有较高的竞争力与较大的发展空间。煤基活性炭在催化领域应用现状主要体现在煤基活性炭自身对氧化、还原、卤化、脱氢、裂解、异构化等多种反应具有催化作用,也可作为催化剂的载体,另外还可与其负载的其他物质结合形成络合物催化剂从而达到协同催化的效果。未来需重点关注按应用需求分类生产不同类型的煤基活性炭、优质原料煤的可替代性研究、柱状活性炭新型黏结剂开发、活性炭改性新型技术研究与活性炭产业标准体系建立研究等方向。煤基活性炭作为新材料与碳素材料的重要分支,将会在我国经济的可持续发展中发挥着越来越重要的作用。
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Abstract
Coal⁃based activated carbon application is an important part of the clean and efficient use of coal. Basedon the characteristics of coal⁃based activated carbon with well⁃developed pore structure, stable physicochemical prop⁃erties, excellent adsorption performance, catalytic performance, easy regeneration and so on, it is widely used inmany fields. Therefore, it is of great significance to study and summarise the current status of the research and devel⁃opment trend of the application of coal⁃based activated carbon. This analysis consolidated recent Chinese research oncoal⁃based activated carbon, delineated its application characteristics in principal fields, and scrutinized its role inliquid phase adsorption (including water treatment, food processing, precious metal extraction, and pharmaceuti⁃cals), gas phase adsorption (like flue gas purification and volatile organic compound treatment), catalysis (cata⁃lysts, catalyst carriers, etc.), supercapacitors, electrode materials, soil amelioration, gas separation, cigarettefilters, and other areas. It also considered the future research direction for coal⁃based activated carbon in China.With its diverse uses in purifying municipal tap water, treating domestic and industrial sewage, pharmaceuticalwastewater, and more, coal⁃based activated carbon is of paramount importance. It also finds widespread use in foodprocessing for decolorization, deodorization, and purification, and is significantly utilized in extracting precious met⁃als like gold with activated carbon and purifying and decolorizing pharmaceutical intermediates. In gas phase adsorp⁃tion, its role in flue gas purification and volatile organic compound treatment showcases its technical application prow⁃ess and vast development potential. The current application of coal⁃based activated carbon in catalysis highlights itsintrinsic catalytic function in various reactions including oxidation, reduction, halogenation, dehydrogenation,cracking, isomerization, among others. It also serves as a catalyst carrier and can form complex catalysts by couplingwith other substances loaded on it to achieve a synergistic catalytic effect. Future research should focus on the produc⁃tion of varied types of coal⁃based activated carbon as per application requirements, substitutability studies of high⁃quality raw coal, development of novel binders for columnar activated carbon, exploration of activated carbon modifi⁃cation new type technologies, and the establishment of a standardized system for the activated carbon industry. As asignificant subdivision of new materials and carbon materials, coal⁃based activated carbon is poised to play a crucialrole in the sustainable development of our national economy.
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关键词
煤基活性炭液相吸附气相吸附催化领域发展趋势黏结剂活性炭改性技术
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KeyWords
coal⁃based activated carbon; liquid phase adsorption; gas phase adsorption; catalytic field; develop⁃ment trend; carbon binder; activated carbon modification technology
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基金项目(Foundation)
天地科技股份有限公司科技创新创业资金专项基金资助项目(2023-TD-QN002)
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DOI
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引用格式
陈文凯, 胡子晗, 白效言, 等. 我国煤基活性炭应用研究现状与发展趋势 [ J]. 煤质技术, 2023, 38(3): 1-10.
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Citation
CHEN Wenkai, HU Zihan, BAI Xiaoyan, et al. Application research status and development trend of coal⁃basedactivated carbon in China [J]. Coal Quality Technology, 2023, 38 (3): 1-10.
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