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主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
阴阳离子表面活性剂对煤层自转向酸液的性能影响及优选
  • Title

    Effect and optimization of anionic and cationic surfactants on the performance of self-diverting acids in coal

  • 作者

    苗彦平张金贵郑旭鹤王宏梁折刚谢瑶程卫民

  • Author

    MIAO Yanping;ZHANG Jingui;ZHENG Xuhe;WANG Hongliang;ZHE Gang;XIE Yao;CHENG Weimin

  • 单位

    陕煤集团神木红柳林矿业有限公司中国矿业大学(北京)神木市能源局山东科技大学 安全与环境工程学院

  • Organization
    Shaanxi Coal Group Shenmu Hongliulin Mining Co., Ltd.
    China University of Mining and Technology (Beijing)
    Shenmu Energy Bureau
    College of Safety and Environmental Engineering, Shandong University of Science and Technology
  • 摘要

    针对煤矿粉尘污染严重问题,研究了煤层OAPB自转向酸液均匀布酸,从而提高煤体含水率,借助黏度、荷电性、官能团等方法研究了不同阴阳离子表面活性剂对自转向酸液增黏、润湿性能的影响规律,探究了性能变化的内部原因,并根据测试结果进行了优选。结果表明:阳离子表面活性剂会直接导致自转向酸液破胶,阴离子表面活性剂的添加使自转向酸液黏度增加;SSA/SDBS润湿性能较好,表面张力最低为24.12 mN/m;SSA/SDBS-16表面张力值总体较高,自身润湿性能差,对煤体的吸附性能也较弱;通过红外实验发现在SSA/SDBS作用下OAPB分子更倾向于形成氢键,并通过三轴渗流实验验证了自转向酸液的渗流效果。

  • Abstract

    Aiming at the serious problem of dust pollution in coal mines, the OAPB automatic diverting acid solution of coal seams was studied to uniformly distribute acid, so as to improve the water content of coal bodies. In order to achieve better results in coal mines, this paper studied the effects of different anionic and cationic surfactants on the viscosity and wettability of self-diverting acid using methods such as viscosity, chargeability, and functional groups, explored the internal causes of performance changes, and optimized based on the test results. The results show that cationic surfactants can directly cause gel breaking of self-diverting acid, and the addition of anionic surfactants can increase the viscosity of self-diverting acid. SSA/SDBS has good wettability, with a minimum surface tension of 24.12 mN/m; SSA/SDBS-16 has an overall higher surface tension value, poor self-wetting performance, and weaker adsorption performance on the coal bodies. Through infrared experiments, it was found that OAPB molecules tended to form hydrogen bonds under the action of SSA/SDBS, and the percolation effect of self-diverting acid solution was verified through triaxial percolation experiments.

  • 关键词

    粉尘防治粉尘污染自转向酸液阴阳离子表面活性剂抑尘剂

  • KeyWords

    dust prevention and control;dust pollution;self-diverting acid;anion and cation;surfactant;dust suppressant

  • 基金项目(Foundation)
    国家自然科学基金重点资助项目(51934004);陕煤集团神木红柳林矿业有限公司科技创新资助项目(HT[2017]430721)
  • DOI
  • 引用格式
    苗彦平,张金贵,郑旭鹤,等. 阴阳离子表面活性剂对煤层自转向酸液的性能影响及优选[J]. 煤矿安全,2024,55(3):60−65.
  • Citation
    MIAO Yanping, ZHANG Jingui, ZHENG Xuhe, et al. Effect and optimization of anionic and cationic surfactants on the performance of self-diverting acids in coal[J]. Safety in Coal Mines, 2024, 55(3): 60−65.
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  • 图表
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    • 不同表面活性剂自转向酸液黏度图

    图(5) / 表(0)

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