• 论文
主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
矿用喷涂堵漏风自修复材料性能研究及工程应用
  • Title

    Research on performance and engineering application of spray air leakage plugging self-healing material for mining

  • 作者

    胡相明姜永茂吴明跃张茜杨振宇

  • Author

    HU Xiangming;JIANG Yongmao;WU Mingyue;ZHANG Qian;YANG Zhenyu

  • 单位

    山东科技大学 安全与环境工程学院山东科技大学 矿山灾害预防控制省部共建国家重点实验室培育基地

  • Organization
    College of Safety and Environmental Engineering, Shandong University of Science and Technology
    State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology, Shandong University of Science and Technology
  • 摘要

    喷涂堵漏风是防止煤自燃的有效手段之一。针对传统水泥基喷涂堵漏风材料脆性大、易开裂、堵漏风效果差的弊端,提出以微生物及结晶矿物为自愈合剂,研制出生物胶囊和矿物胶囊以及一种生物–矿物–纤维协同自修复材料。研究了不同养护湿度和养护时间对材料裂缝自修复能力的影响。结果表明:当养护湿度为100%相对湿度、养护时间为35 d时,研制的生物胶囊和矿物胶囊可以将裂缝完全修复,裂缝最大修复宽度为μm。采用扫描电子显微镜(SEM)和X射线能谱仪(EDS)探究了自修复材料裂缝区域修复产物的晶型及元素组成,发现裂缝处的修复产物为球碳镁石、花瓣状的水菱镁矿以及大量由细菌矿化产生的球形方解石,这些修复产物在一定程度上起到了密闭裂缝的作用;EDS能谱分析证实了修复产物为MgCO3和CaCO3。当养护湿度为100%时,材料具有最高的堵漏风率(97.15%),比同养护条件的对照组试样高出73.62%。最后将自修复材料用于沿空煤柱喷涂堵漏风,结果显示该材料在6个月内未发现明显裂隙,与传统水泥砂浆相比,该材料具有更长的使用寿命和更好的预防效果。

  • Abstract

    Spray air leakage plugging is one of the effective means to prevent coal spontaneous combustion. Aiming at the drawbacks of high brittleness, easy cracking, and poor air leakage plugging effectiveness of traditional cement-based spraying air plugging material, biological capsule, mineral capsule and bio-mineral-fiber synergistic self-healing material were developed with microorganisms and crystalline minerals as self-healing agents. The influence of different curing humidity and curing time on the self-healing ability of material cracks was studied. The results showed that when the curing humidity was 100%, and the curing time was 35 days, the biological and mineral capsules could completely heal the cracks, with a maximum healing width ofμm. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) were used to investigate the crystal structure and elemental composition of the healing products in the crack area of self-healing material. It was found that the healing products at the crack were spherical magnesite, petal-shaped hydromagnesite, and a large amount of spherical calcite produced by bacterial mineralization, which to some extent played a role in sealing the crack. EDS analysis confirmed that the healing products were MgCO3 and CaCO3. When the curing humidity was 100%, the material had the highest air leakage plugging rate (97.15%), which was 73.62% higher than the control group samples under the same curing conditions. Finally, self-healing material was used for spraying and plugging air leakage along the coal pillar, and the results showed that no obvious cracks were found within 6 months. Compared with traditional cement mortar, self-healing material has a longer service life and better prevention effect.

  • 关键词

    喷涂堵漏风材料煤自燃裂缝修复愈合剂微生物结晶矿物

  • KeyWords

    spray air leakage plugging material;coal spontaneous combustion;crack repair;healing agent;microorganism;crystalline minerals

  • 基金项目(Foundation)
    国家自然科学基金资助项目(42077444,52304242,42307585)
  • DOI
  • 引用格式
    胡相明,姜永茂,吴明跃,等. 矿用喷涂堵漏风自修复材料性能研究及工程应用[J]. 煤炭科学技术,2024,52(8):83−95.
  • Citation
    HU Xiangming,JIANG Yongmao,WU Mingyue,et al. Research on performance and engineering application of spray air leakage plugging self-healing material for mining[J]. Coal Science and Technology,2024,52(8):83−95.
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