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主办单位:煤炭科学研究总院有限公司、中国煤炭学会学术期刊工作委员会
低温液氮作用下煤体瓦斯吸附特性试验研究
  • Title

    Experimental study on coal gas adsorption characteristics under action of low temperature liquid nitrogen

  • 作者

    秦雷林海飞兰世瑞赵鹏翔严敏

  • Author

    QINLei LIN Haifei LAN Shirui ZHAO Pengxiang YAN Min

  • 单位

    西安科技大学西部矿井开采及灾害防治教育部重点实验室,西安科技大学安全科学与工程学院

  • Organization
    Key Laboratory of Western Mine Exploitation and Hazard Prevention,Ministry of Education,Xi'an University of
    Science and Technology College of Safety Science and Engineering,Xi'an University of Science and Technology
  • 摘要

    液氮致裂煤层增透技术具有良好的发展前景,而针对低温液氮作用下煤体瓦斯吸附特性研究目前尚不完善,大部分研究处于初步研究阶段;为了对液氮冻融作用及试验初始温度作用下的煤体瓦斯吸附特性变化规律及变化趋势进行研究,选取新疆硫磺沟煤矿煤样作为研究对象,利用PCTPro高压气体吸附仪对试验煤样在不同液氮冻融时间(0、30、60、90、120min)及不同试验初始温度(30、40、50、60、70℃)条件下的吸附特性进行了研究,得出了不同液氮冻融时间及不同试验初始温度条件下煤体瓦斯吸附量、吸附增量及煤体瓦斯饱和吸附量的变化,并根据试验结果选取了3种吸附理论模型对试验结果进行拟合,分析拟合效果对吸附理论进行优选。归纳煤体在2个变量影响下吸附特性的变化。研究结果表明:煤体瓦斯吸附量随液氮冻融时间增加而逐渐增大、随试验初始温度增大而逐渐减小;煤体瓦斯饱和吸附量随液氮冻融时间增加呈上升趋势、随试验初始温度增加呈下降趋势。在2个变量条件下进行不同理论模型拟合,结果表明Langmuir理论模型拟合效果最好,其拟合度最高,误差范围小;2个变量影响条件下,Langmuir理论模型中吸附常数b无明显规律,其影响因素包含多种,而吸附常数a随液氮冻融时间增加逐渐增大、随试验初始温度增加逐渐减小。



  • Abstract
    Liquid nitrogen cracking coal seam permeability technology has good prospects,but research on the gas adsorption characteristics of coal body under th e action of low temperature liquid nitrogen is still not perfect,and most of the research is in the preliminary research stage. In order to study coal gas adsorption charact eristics under the action of liquid nitrogen freezing-thawing and the initial temperature,the change law and trend of coal gas absorption characteristics under the action of the coal are studied. A coal sample from Xinjiang Sulgougou Coal Mine was selected to study the adsorption characteristics under different liquid nitrogen freeze-tha W time( 0,30,60,90, 120 min)and the different initial temperature( 30,40,50,60,70 °C) using PCTPro high pressure adsorption apparatus. Through the study,the change of adsorption capacity,adsorption of increment and the saturated adsorption amount under the condition of different liquid nitrogen freezethaw time and initial temperature were obtained,three kinds of adsorption theory models were selected to fit the experimental results. The variation of coal adsorption characteristics under the influence of two variables were concluded. The results show that the coal gas adsorption capacity gradually increases with the increase of freeze-thaw time and decreases with t he increase of initial temperature. The saturated adsorption capacity increases with the increase of liquid nitrogen freeze-thaw time. The initial temperature increase of t he test showed a downward trend. Fitting different theoretical models under two-variable conditions,the results show that the Langmuir theoretical model has the best fit ting effect,the highest degree of fit,and a small error range.Under the condition of two variables,there is no obvious rule for adsorption constant b value,while the adsorp tion constant a increases with the increase of liquid nitrogen freezing-thawing time and decreases with the increase of initial temperature.
  • 关键词

    煤层气液氮冻融初始温度瓦斯吸附等温吸附

  • KeyWords

    coalbed methane; liquid nitrogen freezing and thawing; initial temperature; gas adsorption; isothermal adsorption;

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